116488-03-0Relevant articles and documents
Trialkylmanganate mediated radical addition of triphenylgermane to carbon-carbon multiple bonds
Kinoshita,Kakiya,Oshima
, p. 2159 - 2160 (2007/10/03)
Treatment of 1-dodecyne with triphenylgermane in the presence of catalytic amounts of tributylmanganate at 25 °C provided 1-triphenylgermyl-1-dodecene in good yield. The reaction proceeded in a radical pathway and treatment of diene afforded the correspon
ET3B Induced Stereoselective Radical Addition of Ph3GeH to Acetylenes and its Application to Isomerization of Olefins
Ichinose, Yoshifumi,Nozaki, Kyoko,Wakamatsu, Kuni,Oshima, Koichiro,Utimoto, Kiitiro
, p. 3709 - 3712 (2007/10/02)
Triphenylgermane adds easily to acetylenes in the presence of Et3B to give (E)- or (Z)-alkenyltriphenylgermanes, respectively, under excellent control of regio- and stereoselectivities.