1166183-85-2Relevant articles and documents
Copper-catalyzed N-arylation of tert-butyl N-sulfonylcarbamates with diaryliodonium salts at room temperature
Moon, Soo-Yeon,Koh, Moonjee,Rathwell, Kris,Jung, Seo-Hee,Kim, Won-Suk
supporting information, p. 1566 - 1573 (2015/03/04)
A new and mild synthetic approach for the synthesis of N-arylsulfonamides under copper-catalyzed conditions at room temperature has been developed. The reaction employs various tert-butyl N-sulfonylcarbamates and diaryliodonium salts to avoid potential genotoxic impurities. A one-pot coupling/Boc-deprotection sequence is also reported to provide mono N-arylsulfonamides in good to excellent yields.