1167421-93-3

Basic information

• Product Name: (fluoromethylene)dicyclohexane
• Synonyms: (fluoromethylene)dicyclohexane
• CAS NO: 1167421-93-3
• Molecular Weight: 198.324
• Mol File: 1167421-93-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (fluoromethylene)dicyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: (fluoromethylene)dicyclohexane(1167421-93-3)
• EPA Substance Registry System: (fluoromethylene)dicyclohexane(1167421-93-3)

Safety Data

• Hazardous Substances Data: 1167421-93-3(Hazardous Substances Data)

Upstream product

• 52034-92-1 dicyclohexylacetic acid 

Relevant articles and documents

Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor

Herein we disclose a deoxyfluorination of alcohols with an electrophilic fluorine source via visible-light photoredox catalysis. This radical-mediated C–F coupling is capable of fluorinating secondary and tertiary alcohols efficiently, complementing previously reported nucleophilic deoxyfluorination protocols.

Fluorodecarboxylation, rearrangement and cyclisation: the influence of structure and environment on the reactions of carboxylic acids with xenon difluoride

The reactions of structurally diverse carboxylic acids with XeF2 in both CH2Cl2/Pyrex and CH2Cl2/PTFE have been studied. Pyrex appears to be a very effective heterogeneous catalyst for an electrophilic mode of reaction of polarised XeF2, leading to rearrangement, cyclisation and cationic products. In CH2Cl2/PTFE, fluorodecarboxylation is the main mode of reaction, in accordance with previous studies, and may occur via a SET reaction of unpolarised XeF2.