116833-54-6Relevant articles and documents
Scrambling of oxygen-18 during the "Borderline" solvolysis of 1-(3-nitrophenyl)ethyl tosylate
Tsuji, Yutaka,Toteva, Maria M.,Amyes, Tina L.,Richard, John P.
, p. 3633 - 3636 (2004)
(Chemical Equation Presented) There is substantial isomerization (k iso = 0.32 x 10-3 s-1) of 3-NO 2C6H413CH(Me)OS(18O) 2ToS during solvolysis (ksolv/
Ion pairs in the solvolysis of secondary systems. Salt effect, 18O-labeling, and polarimetric studies of 1-(4′-tolyl)-2,2,2-trifluoroethyl tosylate
Allen, Annette D.,Fujio, Mizue,Tee, Oswald S.,Tidwell, Thomas T.,Tsuji, Yutaka,Tsuno, Yuho,Yatsugi, Ken-Ichi
, p. 8974 - 8981 (1995)
The effect of added trifluoroacetate and Inflate salts on the trifluoroacetolysis of 1-(4′-tolyl)-2,2,2-trifluoroethyl tosylate has been studied, including reactions of optically active and 18O-labeled substrates. With no added salt the polarim
