116981-02-3

Basic information

• Product Name: Silane, [(3-iodo-2-methyl-1-phenyl-1-propenyl)oxy]trimethyl-
• CAS NO: 116981-02-3
• Molecular Formula: C13H19IOSi
• Molecular Weight: 346.283
• Mol File: 116981-02-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, [(3-iodo-2-methyl-1-phenyl-1-propenyl)oxy]trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(3-iodo-2-methyl-1-phenyl-1-propenyl)oxy]trimethyl-(116981-02-3)
• EPA Substance Registry System: Silane, [(3-iodo-2-methyl-1-phenyl-1-propenyl)oxy]trimethyl-(116981-02-3)

Safety Data

• Hazardous Substances Data: 116981-02-3(Hazardous Substances Data)

Upstream product

• 16029-98-4 trimethylsilyl iodide 
• 769-60-8 2-methyl-1-phenylprop-2-en-1-one 

Downstream Products

• 116981-07-8 (3-Iodomethyl-3,5-dimethyl-2,6-diphenyl-3,4-dihydro-2H-pyran-2-yloxy)-trimethyl-silane 
• 72357-49-4 2-benzoyl-1-iodo-2-methylpropene 
• 769-60-8 2-methyl-1-phenylprop-2-en-1-one 

Relevant articles and documents

Preparation and Reactivities of (η3-1- and 2-Trimethylsiloxyallyl)Fe(CO2)NO Complexes. Intermediates Functioning as Equivalents of β- and α-Acyl Carbocations and Acyl Carbanions

(η3-1- and 2-Trimethylsiloxyallyl)Fe(CO)2NO complexes were prepared by the reaction of the corresponding siloxyallylic halides with Bu4N.These complexes reacted with both of carbon nucleophiles and carbon electrophiles preferentially at the less hindered sites of the allylic ligands.In these reactions, (η3-1-trimethylsiloxyallyl)Fe(CO)2NO complexes served as synthetically equivalent synthons for both of β-acyl carbocations and β-acyl carbanions and (η3-2-trimethylsiloxyallyl)Fe(CO)2NO complexes as both of α-acyl carbocations and α-acyl carbanions.The stereochemical courses of the reactions are described.