117106-36-2

Basic information

• Product Name: MESO-1,2-BIS(4-METHOXYPHENYL)ETHYLENEDIAMINE
• Synonyms: MESO-1,2-BIS(4-METHOXYPHENYL)-1,2-DIAMINOETHANE;MESO-1,2-BIS(4-METHOXYPHENYL)ETHYLENEDIAMINE;MOED;meso-1,2-Bis(4-methoxyphenyl)-1,2-diaminoethane, MOED;(1S,2R)-1,2-Bis(4-methoxyphenyl)ethylenediamine
• CAS NO: 117106-36-2
• Molecular Formula: C16H20N2O2
• Molecular Weight: 272.34
• Mol File: 117106-36-2.mol
• Article Data: 18

Chemical Properties

• Melting Point: 150-155 °C(lit.)
• Boiling Point: 438.2°C at 760 mmHg
• Flash Point: 231.9°C
• Appearance: /
• Density: 1.135g/cm³
• Vapor Pressure: 7.01E-08mmHg at 25°C
• Refractive Index: 1.588
• CAS DataBase Reference: MESO-1,2-BIS(4-METHOXYPHENYL)ETHYLENEDIAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: MESO-1,2-BIS(4-METHOXYPHENYL)ETHYLENEDIAMINE(117106-36-2)
• EPA Substance Registry System: MESO-1,2-BIS(4-METHOXYPHENYL)ETHYLENEDIAMINE(117106-36-2)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• F: 8-10-34
• Hazardous Substances Data: 117106-36-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H20N2O2/c1-19-13-7-3-11(4-8-13)15(17)16(18)12-5-9-14(20-2)10-6-12/h3-10,15-16H,17-18H2,1-2H3/t15-,16+

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 58546-78-4 C₃₀H₂₈N₂O₄ 
• 64-17-5 ethanol 
• 3717-21-3 p-methoxyl benzaldoxime 
• 41097-47-6 N,N'-Bis-[1-(4-methoxy-phenyl)-meth-(E)-ylidene]-hydrazine 
• 58519-97-4 meso-N,N'-bis(4-methoxybenzylidene)-1,2-bis(4-methoxyphenyl)ethylenediamine 
• 132127-28-7 N-trimethylsilyl-(4-methoxybenzaldimine) 
• 144406-64-4 [(1R,2R)-2-Benzyloxycarbonylamino-1,2-bis-(4-methoxy-phenyl)-ethyl]-carbamic acid benzyl ester 
• 169532-38-1 (3S,5R,6R,8S)-3,8-Diisopropyl-5,6-bis-(4-methoxy-phenyl)-1,10-dioxa-4,7-diaza-cyclotridecane-2,9-dione 
• 4464-76-0 1,2-bis(4-methoxyphenyl)-1,2-ethanediol 
• 1226-42-2 1,2-bis(4-methoxyphenyl)-1,2-ethanedione 
• 45821-44-1 4-methoxy-benzylideneamine 
• 58519-97-4 (1R,2S)-1,2-Bis-(4-methoxy-phenyl)-N,N'-bis-[1-(4-methoxy-phenyl)-meth-(E)-ylidene]-ethane-1,2-diamine 
• 51208-43-6 meso-1,2-bis-(p-methoxyphenyl)-ethylenediamine 

Downstream Products

• 530-34-7 2-amino-1,2-dianisylethanol 
• 58519-97-4 (1R,2S)-1,2-Bis-(4-methoxy-phenyl)-N,N'-bis-[1-(4-methoxy-phenyl)-meth-(E)-ylidene]-ethane-1,2-diamine 
• 1413934-30-1 2,2,2-trichloroethyl((1R,2R)-2-benzamido-1,2-bis(4-methoxyphenyl)ethyl)carbamate 
• 1413934-40-3 bis(2,2,2-trichloroethyl)((1R,2R)-1,2-bis(4-methoxyphenyl)ethane-1,2-diyl)dicarbamate 
• 1429397-54-5 C₂₃H₂₀Br₄N₂O₆S 
• 1429397-53-4 C₂₃H₂₄N₂O₆S 
• 1436431-43-4 C₆₆H₆₈N₂O₁₀ 
• 1619263-28-3 C₅₇H₅₄N₆O₆ 
• 1599484-91-9 C₃₈H₄₂N₄O₈S₂ 

Relevant articles and documents

Syntheses of Families of Enantiopure and Diastereopure Cobalt Catalysts Derived from Trications of the Formula [Co(NH2CHArCHArNH2)3]3+

Aerobic reactions of CoX2 (X = OAc, Cl) or Co(ClO4)2 with (S,S)-1,2-diphenylethylenediamine [(S,S)-dpen] in CH3OH, followed by HCl or HClO4 additions, give the diastereomeric lipophobic salts Λ-[Co((S

Reaction of aromatic aldehydes with ammonium acetate

By reaction of aromatic aldehydes with ammonium acetate a series of 1,2-diaryl-1,2-diamino-ethanes and their derivatives was obtained. The mechanism of reaction was suggested and its principal stages were proved. Reactions with ammonium acetate of aromatic aldehydes containing ortho-substituents resulted in the corresponding 2,4,5-triaryl-4,5-dihydroimidazoles.

Diboron glycol ester as well as preparation method, intermediate and application thereof

The invention discloses diboron glycol ester as well as a preparation method, an intermediate and application thereof. The diboron glycol ester can be used for inducing reductive coupling reaction with imine as a substrate, and the substrate can be obtained by reaction of aldehyde and ammonia and is very easy to obtain and quite low in cost. The product can be separated from a reaction system onlyby acid-base operation without column chromatography purification, and the post-treatment mode is convenient and easy to operate. The yield of the obtained product is high, and protective group operation is not needed. The diboron glycol ester has chirality, the stereoselectivity of the reductive coupling reaction is generally excellent, and 99% ee chiral diamine can be obtained only through simple recrystallization. The diboron glycol ester can be obtained by reacting diol with diboron glycol ester, the diol is convenient to prepare and easy to amplify, the diol can be recycled from a reaction solution through simple acid-base operation, the recovery rate reaches 95%, and the preparation cost is further saved.

Chemoselective Photoredox Synthesis of Unprotected Primary Amines Using Ammonia

Unprotected α-amino carbon radicals are produced as novel intermediates via a transformation that merges acid-promoted N-H imine generation and chemoselective photocatalytic single-electron reduction. Coupling ammonia and aldehydes/ketones allows the generation of primary amines under mild conditions without the need for protecting groups. The key intermediate can be efficiently transformed into primary (di)amines by a formal dimerization, reductive amination via hydrogen atom transfer, and arylation through radical-radical coupling.