117205-75-1Relevant articles and documents
Electrocatalytical carboxylation of primary and secondary amines; alternative synthesis of urethanes
Hess Komenda,Hollwarth,Dunkel
, p. 848 - 851 (2007/10/02)
Electrocatalytical carboxylation of 13 no-reducible primary and secondary amines lead in CO2-saturated DMF to known and new carbamates. Electrochemical results correlated with MNDO-calculation and potential curves proved, that the new, general and regioselective carboxylation method proceed via amin-CO2-radicalanion initiation, followed by SET-reaction inside an self-reproducing process.