1172640-31-1

Basic information

• Product Name: 1-bromo-2,4-bis(dec-9-enyloxy)benzene
• Synonyms: 1-bromo-2,4-bis(dec-9-enyloxy)benzene
• CAS NO: 1172640-31-1
• Molecular Weight: 465.514
• Mol File: 1172640-31-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-bromo-2,4-bis(dec-9-enyloxy)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromo-2,4-bis(dec-9-enyloxy)benzene(1172640-31-1)
• EPA Substance Registry System: 1-bromo-2,4-bis(dec-9-enyloxy)benzene(1172640-31-1)

Safety Data

• Hazardous Substances Data: 1172640-31-1(Hazardous Substances Data)

Upstream product

• 6626-15-9 4-Bromoresorcinol 
• 131034-47-4 10-iodo-1-decene 
• 13019-22-2 9-Decen-1-ol 

Downstream Products

• 1172640-33-3 2,4-bis(dec-9-enyloxy)phenylboronic acid 

Relevant articles and documents

Concave 1,10-phenanthrolines as ligands for cyclopropanations - Towards a deeper understanding of the stereoselectivity

Four new mono- and bimacrocyclic 1,10-phenanthrolines - 3b and 4a-c - containing aryl bridgeheads have been synthe- sised. The etherification of the aryl bridgeheads was accomplished by Williamson or Mitsunobu reactions. A key step in the synthesis of the macrocyclic phenanthrolines 3 and 4 is the Suzuki coupling of 2,9-diiodo-1,10-phenan- throline (12) with the appropriately substituted boronic acids 17 and 20. Ring-closing metathesis and hydrogenation completed the synthesis. The resulting macrocyclic 1,10-phenan- throlines 3b and 4a-c were tested as ligands in a copper(I)- catalysed stereoselective cyclopropanation.