1173936-88-3Relevant articles and documents
Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of β,γ-unsaturated ketones
Randell-Sly, Helen E.,Osborne, James D.,Woodward, Robert L.,Currie, Gordon S.,Willis, Michael C.
experimental part, p. 5110 - 5117 (2009/12/03)
A variety of β-S-substituted aldehydes undergo efficient and regioselective rhodium catalyzed hydroacylation reactions with 1,3-disubstituted and 1,1,3-trisubstituted allenes, to deliver β,γ-unsaturated ketone products. Regioselectivites are controlled pr