117417-05-7

Basic information

• Product Name: trans-p-acetyl-β-bromostyrene
• Synonyms: trans-p-acetyl-β-bromostyrene
• CAS NO: 117417-05-7
• Molecular Weight: 225.085
• Mol File: 117417-05-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-p-acetyl-β-bromostyrene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-p-acetyl-β-bromostyrene(117417-05-7)
• EPA Substance Registry System: trans-p-acetyl-β-bromostyrene(117417-05-7)

Safety Data

• Hazardous Substances Data: 117417-05-7(Hazardous Substances Data)

Upstream product

• 75883-03-3 4'-(2-trimethylsilylethynyl)acetophenone 
• 99-90-1 para-bromoacetophenone 
• 14275-61-7 (E)-1,2-bis(tri-n-butylstannyl)ethene 
• 13329-40-3 4-Iodoacetophenone 

Downstream Products

• 1266052-59-8 C₂₅H₂₈N₆O₅ 
• 1266052-68-9 C₂₂H₂₃N₅O₅ 

Relevant articles and documents

Regio- and stereoselective synthesis of bromoalkenes by homolytic hydrobromination of alkynes with hydrogen bromide

Homolytic hydrobromination of terminal and internal alkynes with a commercially available solution of hydrogen bromide in acetic acid has been investigated for regio- and stereoselective synthesis of bromoalkenes. Under an aerobic atmosphere at room temperature, the reaction of ethynylarenes with a small excess of HBr efficiently gave (2-bromoethenyl)arenes with good to high E-selectivity. (Alk-1-ynyl)arenes, or internal alkynes bearing both phenyl and alkyl groups at the sp-carbons also underwent the air-initiated hydrobromination to exhibit high Z-selectivity under kinetic conditions using a half equivalent of HBr.