117417-12-6Relevant articles and documents
Palladium(0) Catalyzed Coupling of trans-1,2-Bis(tri-n-butylstannyl)ethylene with Aromatic Halides: A convenient Synthesis of Substituted trans-β-Bromostyrenes
Haack, Richard A.,Penning, Thomas D.,Djuric, Stevan W.,Dziuba, John A.
, p. 2783 - 2786 (1988)
trans-β-Bromostyrenes have been conveniently prepared in moderate to high yield in a one-pot two-step sequence. trans-1,2-Bis(tri-n-butylstannyl)ethylene underwent a smooth palladium(0) catalyzed coupling reaction with 0.5 equivalents of aromatic bromide or iodide to furnish a trans-β-stannylstyrene.This intermediate vinyl stannane, without isolation, was then converted to the substituted trans-bromostyrene on treatment with molecular bromine.