117423-68-4

Basic information

• Product Name: (Z)-2,2-dimethyl-1,3-propanediyl α-acetyl-3-nitrostyrylphosphonate
• Synonyms: (Z)-2,2-dimethyl-1,3-propanediyl α-acetyl-3-nitrostyrylphosphonate
• CAS NO: 117423-68-4
• Molecular Weight: 339.285
• Mol File: 117423-68-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-2,2-dimethyl-1,3-propanediyl α-acetyl-3-nitrostyrylphosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2,2-dimethyl-1,3-propanediyl α-acetyl-3-nitrostyrylphosphonate(117423-68-4)
• EPA Substance Registry System: (Z)-2,2-dimethyl-1,3-propanediyl α-acetyl-3-nitrostyrylphosphonate(117423-68-4)

Safety Data

• Hazardous Substances Data: 117423-68-4(Hazardous Substances Data)

Upstream product

• 40891-03-0 3-(dimorpholinomethyl)-1-nitrobenzene 
• 111011-80-4 2-acetonyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphorinane 
• 99-61-6 3-nitro-benzaldehyde 

Downstream Products

• 774235-80-2 C₄₁H₄₄N₃O₈P 

Relevant articles and documents

Novel synthesis of α-acetylstyrylphosphonates

α-Acetylstyrylphosphonates were conveniently synthesized from 2-oxopropylphosphonates and substituted (dimorpholinomethyl)-benzenes (animals). 4-Benzylidenemorpholinium carboxylates, generated from animals by the action of α-halo acids, reacted with the phosphonates to give the products by elimination of the amine. The yields were influenced by the nature of substituents and their position in the phenyl ring and could be improved by adjustment of the acidities of the reacted acids. α-Acetylstyrylphosphonates containing various substituents on every position (at the 2-, 3-, or 4-position) in the phenyl ring were obtained generally in excellent yields using monochloroacetic acid.