117653-40-4

Basic information

• Product Name: (2S,4S)-4-(Imidazole-1-carbothioyloxy)-pyrrolidine-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester
• Synonyms: (2S,4S)-4-(Imidazole-1-carbothioyloxy)-pyrrolidine-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester
• CAS NO: 117653-40-4
• Molecular Weight: 389.432
• Mol File: 117653-40-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,4S)-4-(Imidazole-1-carbothioyloxy)-pyrrolidine-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4S)-4-(Imidazole-1-carbothioyloxy)-pyrrolidine-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester(117653-40-4)
• EPA Substance Registry System: (2S,4S)-4-(Imidazole-1-carbothioyloxy)-pyrrolidine-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester(117653-40-4)

Safety Data

• Hazardous Substances Data: 117653-40-4(Hazardous Substances Data)

Upstream product

• 57653-35-7 (2S,4S)-4-hydroxypyrrolidine-1,2-dicarboxylic acid 1-benzyl 2-methyl 
• 6160-65-2 1,1'-Thiocarbonyldiimidazole 

Downstream Products

• 115545-74-9 Cbz-4-(2-cyanoethyl)-Pro-OMe 
• 117653-45-9 (1R,5R)-4-((1R,2S)-1-Carboxy-2-methyl-butylamino)-3-cyano-6-aza-bicyclo[3.2.1]oct-3-ene-6-carboxylic acid benzyl ester 
• 117653-45-9 (1S,5S)-4-((1S,2S)-1-Carboxy-2-methyl-butylamino)-3-cyano-6-aza-bicyclo[3.2.1]oct-3-ene-6-carboxylic acid benzyl ester 
• 115545-81-8 4-(1-tert-Butoxycarbonyl-ethylamino)-3-cyano-6-aza-bicyclo[3.2.1]oct-3-ene-6-carboxylic acid benzyl ester 
• 115545-80-7 methyl N-<4-<6-(benzyloxycarbonyl)-3-cyano-6-azabicyclo<3.2.1>oct-2-enyl>>-L-alaninate 
• 115545-76-1 6-(benzyloxycarbonyl)-3-cyano-4-keto-6-azabicyclo<3.2.1>octane 
• 115545-79-4 6-(benzyloxycarbonyl)-3-cyano-4-chloro-6-azabicyclo<3.2.1>oct-3-ene 

Relevant articles and documents

Amino Acid Derivatives That Stabilize Secondary Structures of Polypeptides. 4. Practical Synthesis of 4-(Alkylamino)-3-cyano-6-azabicyclooct-3-enes (Ben Derivatives) as γ-Turn Templates

A practical synthesis of the conformationally restricted amino acid analogue methyl N-oct-2-enyl>>-L-alaninate (12ab) from 4-hydroxyproline is described.Blocking and Barton cyanoethylation generates N-(