1176891-21-6Relevant articles and documents
A catalytic, Bronsted base strategy for intermolecular allylic C-H amination
Reed, Sean A.,Mazzotti, Anthony R.,White, M. Christina
supporting information; experimental part, p. 11701 - 11706 (2009/12/08)
A Bronsted base activation mode for oxidative, Pd(II)/sulfoxide- catalyzed, intermolecular C-H allylic amination is reported. N,N-diisopropylethylamine was found to promote amination of unactivated terminal olefins, forming the corresponding linear allylic amine products with high levels of stereo-, regio-, and chemoselectivity. The predictable and high selectivity of this C-H oxidation method enables latestage incorporation of nitrogen into advanced synthetic intermediates and natural products.
