117749-19-6

Basic information

• Product Name: (E)-1,4-diphenyl-3-(phenylsulphonyl)-1-butene
• Synonyms: (E)-1,4-diphenyl-3-(phenylsulphonyl)-1-butene
• CAS NO: 117749-19-6
• Molecular Weight: 348.466
• Mol File: 117749-19-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-1,4-diphenyl-3-(phenylsulphonyl)-1-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1,4-diphenyl-3-(phenylsulphonyl)-1-butene(117749-19-6)
• EPA Substance Registry System: (E)-1,4-diphenyl-3-(phenylsulphonyl)-1-butene(117749-19-6)

Safety Data

• Hazardous Substances Data: 117749-19-6(Hazardous Substances Data)

Upstream product

• 16212-07-0 trans-cinnamyl phenyl sulfone 
• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 

Downstream Products

• 27066-35-9 (E)-1,4-diphenylbut-1-ene 
• 1142-22-9 (E)-1,4-diphenylbut-2-ene 
• 886-65-7 trans,trans-1,4-Diphenyl-1,3-butadiene 

Relevant articles and documents

Integrated chemical process. Construction of highly substituted allylic moieties from allylic sulfones in one-pot

According to 'integrated chemical process', a novel one-pot process for construction of highly substituted allylic moieties has been achieved. A series of alkylation of allylic sulfones and palladium-catalyzed reductive desulfonylation by use of LiBHEt3 is integrated. The double alkylation furnishes more substituted olefins. Use of arylzinc compounds in place of the hydride enables electrophilic alkylation/nucleophilic arylation in one-pot. The integrated process provides higher overall yields than the corresponding stepwise process.

Phase transfer catalysis (ptc): a convenient tool for generation and reactions of allyl sulphonyl carbanions

Allyl sulphones la-d or le react with alkyl halides (RX) in the presence of concentrated aqueous NaOH solution and tetrabutylammonium bromide (TBAB) as a catalyst to give, with high yields, mono(2a-d) or di-alkylated (3e) products, respectively. Under the same conditions sulphone If forms mixtures of the products, the composition of which depends on the structure of RX and the RX:lf ratio. With a,cu-dibromo alkanes, sulphones la,d-f give rise to cyclic products (7a,d-f) with low to excellent yields. With 4-nitrofluorobenzene (in solid NaOH-DMSO system) or vinyl acetate (by PTC) sulphone la affords the products 2al3 and 9a, respectively.