117773-78-1

Basic information

• Product Name: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (5R)-
• CAS NO: 117773-78-1
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Mol File: 117773-78-1.mol
• Article Data: 65

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (5R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (5R)-(117773-78-1)
• EPA Substance Registry System: Cyclohexanone, 5-methyl-2-(1-methylethyl)-, (5R)-(117773-78-1)

Safety Data

• Hazardous Substances Data: 117773-78-1(Hazardous Substances Data)

Upstream product

• 89-82-7 pulegone 
• 72311-09-2 3-Methyl-6-(1-methylethyl)-1-trimethylsilyloxy-1-cyclohexen 
• 75-36-5 acetyl chloride 
• 106-95-6 allyl bromide 
• 59781-47-4 r-2-Acetyl-t-3-methyl-c-6-(1-methylethyl)-1-cyclohexanon 
• 74-88-4 methyl iodide 
• 6485-40-1 (R)-Carvone 
• 1214906-07-6 (-)-menthol 
• 89-82-7 pulegone 
• 89-83-8 thymol 
• 15356-70-4 menthol 
• 36392-06-0 3,7-dimethyl-6-octenoyl chloride 
• 99-82-1 Menthane 
• 115033-76-6 Se-phenyl 3,7-dimethyloct-6-eneselenoate 

Downstream Products

• 13143-66-3 (+/-)-isonicotinic acid menthylidenehydrazide 
• 1538-17-6 (+/-)-Menthon-2,4-DNP 
• 15356-60-2 (1S,2R,5S)-(+)-menthol 
• 2216-51-5 (-)-menthol 
• 490-99-3 DL-neomenthol 
• 15356-70-4 menthol 
• 491-07-6 isomenthone 
• 907166-70-5 N'-[5-methyl-2-(propan-2-yl)cyclohexylidene]pyridine-3-carbohydrazide 
• 13143-66-3 C₁₆H₂₃N₃O 
• 1299427-55-6 C₁₇H₂₃FN₂O 
• 904248-90-4 N'-[5-methyl-2-(propan-2-yl)cyclohexylidene]benzohydrazide 
• 1299427-51-2 4-hydroxy-N'-[5-methyl-2-(propan-2-yl)cyclohexylidene]benzohydrazide 
• 1299427-53-4 4-chloro-N'-[5-methyl-2-(propan-2-yl)cyclohexylidene]benzohydrazide 
• 1299427-52-3 N'-[5-methyl-2-(propan-2-yl)cyclohexylidene]-4-nitrobenzohydrazide 

Relevant articles and documents

Efficient conjugate reduction of α,β-unsaturated carbonyl compounds by complexation with aluminum tris(2,6-diphenylphenoxide)

-

Organotin hydride-catalyzed conjugate reduction of α,β-unsaturated ketones

-

Rapid, chemoselective and mild oxidation protocol for alcohols and ethers with recyclable N-chloro-N-(phenylsulfonyl)benzenesulfonamide

Chlorine is the 20th most abundant element on the earth compared to bromine, iodine, and fluorine, a sulfonimide reagent, N-chloro-N-(phenylsulfonyl)benzenesulfonamide (NCBSI) was identified as a mild and selective oxidant. Without activation, the reagent was proved to oxidize primary and secondary alcohols as well as their symmetrical and mixed ethers to corresponding aldehydes and ketones. With recoverable PS-TEMPO catalyst, selective oxidation over chlorination of primary and secondary alcohols and their ethers with electron-donating substituents was achieved. The reagent precursor of NCBSI was recovered quantitatively and can be reused for synthesizing NCBSI.

Heterogeneous Ru(iii) oxidation catalysts: Via 'click' bidentate ligands on a periodic mesoporous organosilica support

A 100% monoallyl ring-type Periodic Mesoporous Organosilica (PMO) is prepared as a novel, versatile and exceptionally stable catalytic support with a high internal surface area and 5.0 nm pores. Thiol-ene 'click' chemistry allows straightforward attachment of bifunctional thiols (-NH2, -OH, -SH) which, exploiting the thioether functionality formed, give rise to 'solid' bidentate ligands. [Ru(acac)2(CH3CN)2]PF6 is attached and complex formation on the solid is studied via density functional theory. All resulting solid catalysts show high activity and selectivity in alcohol oxidation reactions performed in green conditions (25 °C/water). The PMO catalysts do not leach Ru during reaction and are thus easily recuperated and re-used for several runs. Furthermore, oxidation of poorly water-soluble (±)-menthol illustrates the benefits of using hydrophobic PMOs as catalytic supports.