1178899-43-8

Basic information

• Product Name: (4-bromophenyl)(imino)(perfluorobutyl)-λ⁶-sulfanone
• Synonyms: (4-bromophenyl)(imino)(perfluorobutyl)-λ⁶-sulfanone
• CAS NO: 1178899-43-8
• Molecular Weight: 438.111
• Mol File: 1178899-43-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (4-bromophenyl)(imino)(perfluorobutyl)-λ⁶-sulfanone(CAS DataBase Reference)
• NIST Chemistry Reference: (4-bromophenyl)(imino)(perfluorobutyl)-λ⁶-sulfanone(1178899-43-8)
• EPA Substance Registry System: (4-bromophenyl)(imino)(perfluorobutyl)-λ⁶-sulfanone(1178899-43-8)

Safety Data

• Hazardous Substances Data: 1178899-43-8(Hazardous Substances Data)

Upstream product

• 1111-78-0 ammonium carbamate 
• 1178899-47-2 nonafluorobutyl p-bromophenyl sulfoxide 
• 1178899-27-8 N-acetyl-S-(p-bromophenyl)-S-(nonafluorobutyl)sulfilimine 

Downstream Products

• 1421133-01-8 N-trifluoromethylsulfonyl-S-nonafluorobutyl-S-p-bromophenylsulfoximine 
• 1421133-02-9 N-nonafluorobutylsulfonyl-S-nonafluorobutyl-S-p-bromophenylsulfoximine 

Relevant articles and documents

One-Pot Synthesis of Aryl- and Alkyl S-Perfluoroalkylated NH-Sulfoximines from Sulfides

A general efficient one-pot synthesis of S-perfluoroalkylated NH-sulfoximines from sulfides has been developed using phenyliodine diacetate (PIDA) and ammonium carbamate. Remarkable rate enhancement with trifluoroethanol was observed, presumably due to H-bonding effects. These mild and metal-free conditions are compatible with -CH2F, -CFCl2, -CF2H, -CF2Br, -C4F9, and -CF3 groups, in both the alkyl- and aryl series. Based on a 19F NMR analysis, a λ6-acetoxysulfanenitrile intermediate was proposed.

Sulfilimines and sulfoximines by reaction of nitriles with perfluoroalkyl sulfoxides

The species obtained by activation of perfluoroalkylated sulfoxides with trifluoromethanesulfonic anhydride behaves as highly electrophilic entities. Their reaction with nitriles allows a Ritter-like process leading to the new fluorinated acylsulfilimines