117939-92-1

Basic information

• Product Name: n-hexyl phenyl sulfoxide
• CAS NO: 117939-92-1
• Molecular Weight: 210.34
• Mol File: 117939-92-1.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: n-hexyl phenyl sulfoxide(CAS DataBase Reference)
• NIST Chemistry Reference: n-hexyl phenyl sulfoxide(117939-92-1)
• EPA Substance Registry System: n-hexyl phenyl sulfoxide(117939-92-1)

Safety Data

• Hazardous Substances Data: 117939-92-1(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 20451-53-0 Phenyl vinyl sulfoxide 
• 119-61-9 benzophenone 
• 65325-68-0 1-(monofluoromethyl sulfinyl)benzene 
• 21369-64-2 n-hexyllithium 
• 111-25-1 1-bromo-hexane 
• 943-78-2 hexyl phenyl sulfide 
• 3761-92-0 n-hexylmagnesium bromide 
• 871950-84-4 7-(phenylthio)-1,2,3,5,8,8a-hexahydro-5-indolizinone 
• 108-98-5 thiophenol 
• 1116-73-0 trihexylaluminium 
• 98-09-9 benzenesulfonyl chloride 

Downstream Products

• 104306-37-8 1-tert-butyldimethylsiloxyhexyl phenyl sulfide 
• 943-78-2 hexyl phenyl sulfide 

Relevant articles and documents

Iron(III) Amine Bis(phenolate) Complex Immobilized on Silica-Coated Magnetic Nanoparticles: A Highly Efficient Catalyst for the Oxidation of Alcohols and Sulfides

We aimed to immobilize a complex of iron(III) amine bis(phenolate) on silica-coated magnetic nanoparticles as a new magnetically recoverable catalyst (Fe3O4@SiO2-APTES-FeLGDC). Both the chemical nature and the structure of catalyst were confirmed by using field-emission transmission electron microscopy, field-emission scanning electron microscopy, FTIR spectroscopy, thermogravimetric analysis, vibrating sample magnetometry, X-ray photoelectron spectroscopy, XRD, atomic absorption spectroscopy, and elemental analysis. This sustainable catalyst leads to the efficient oxidation of a wide range of alcohols and sulfides with excellent conversion and selectivity under a mild conditions to their corresponding oxidized products, acids (or ketones) and sulfoxides, respectively. Furthermore, the stability of the structure and morphology of our efficient recyclable system was investigated, and all of the data proved that the complex was anchored firmly to the magnetite nanoparticles.

Schiff base complex of Mo supported on iron oxide magnetic nanoparticles (Fe3O4) as recoverable nanocatalyst for the selective oxidation of sulfides

In this work, a new tridentate Schiff base dioxo-molybdenum(VI) complex immobilized on silica-coated magnetic nanoparticles (MoO25CML–Fe3O4@SiO2) has been synthesized and characterized using different techniques such as FTIR, TGA, AAS, ICP–AES, XRD, VSM, EDX and SEM analyses. The catalytic activity of synthesized complex was examined in the oxidation of various sulfides in the presence of H2O2 as cheap, green and eco-friendly oxidant. This catalytic system provides high conversion and selectivity toward either sulfoxides or sulfones under different conditions. Also, the nanocatalyst could be easily separated and regenerated from reaction media by external magnet and could be reused for ten times without significant loss of the activity and selectivity.

1,1,2,2-Tetrahydroperoxy-1,2-diphenylethane as new oxidant for chemoselective and catalyst free oxidation of sulfides to sulfoxides and sulfones

A catalyst free and chemoselective oxidation of sulfides to sulfoxides or sulfones was developed using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane as a new oxidant. This scope has shown the achievement of various sulfoxides and sulfones which were obtained selectively in high yields at room temperature.