1181365-58-1

Basic information

• Product Name: 2-(3,5-diphenyl-1H-pyrazol-1-yl)-1,10-phenanthroline
• Synonyms: 2-(3,5-diphenyl-1H-pyrazol-1-yl)-1,10-phenanthroline
• CAS NO: 1181365-58-1
• Molecular Weight: 398.467
• Mol File: 1181365-58-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(3,5-diphenyl-1H-pyrazol-1-yl)-1,10-phenanthroline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3,5-diphenyl-1H-pyrazol-1-yl)-1,10-phenanthroline(1181365-58-1)
• EPA Substance Registry System: 2-(3,5-diphenyl-1H-pyrazol-1-yl)-1,10-phenanthroline(1181365-58-1)

Safety Data

• Hazardous Substances Data: 1181365-58-1(Hazardous Substances Data)

Upstream product

• 22426-14-8 2--bromo-1,10--phenanthroline 
• 120-46-7 1,3-diphenylpropanedione 
• 77544-92-4 2-hydrazinyl-1,10-phenanthroline 
• 7089-68-1 2-chloro-[1,10]phenanthroline 
• 1145-01-3 3,5-Diphenylpyrazole 

Downstream Products

• 1181578-02-8 dibromo(2-(3,5-diphenylpyrazol-1-yl)-1,10-phenanthroline)nickel(II) 
• 1451010-47-1 C₂₇H₁₈Cl₂FeN₄ 
• 1428871-23-1 2-(3,5-diphenylpyrazol-1-yl)-1,10-phenanthroline cobalt(II) chloride 

Relevant articles and documents

Selective synthesis of mono- and di-methylated amines using methanol and sodium azide as C1 and N1 sources

A Ru(ii) complex mediated synthesis of various N,N-dimethyl and N-monomethyl amines from organic azides using methanol as a methylating agent is reported. This methodology was successfully applied for a one-pot reaction of bromide derivatives and sodium azide in methanol. Notably, by controlling the reaction time several N-monomethylated and N,N-dimethylated amines were synthesized selectively. The practical applicability of this tandem process was revealed by preparative scale reactions with different organic azides and synthesis of an anti-vertigo drug betahistine. Several kinetic experiments and DFT studies were carried out to understand the mechanism of this transformation.