118487-15-3

Basic information

• Product Name: 1-phenylthio-3,4,6-tri-O-t-butyl-dimethylsilyl-D-glucal
• CAS NO: 118487-15-3
• Molecular Weight: 597.095
• Mol File: 118487-15-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-phenylthio-3,4,6-tri-O-t-butyl-dimethylsilyl-D-glucal(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylthio-3,4,6-tri-O-t-butyl-dimethylsilyl-D-glucal(118487-15-3)
• EPA Substance Registry System: 1-phenylthio-3,4,6-tri-O-t-butyl-dimethylsilyl-D-glucal(118487-15-3)

Safety Data

• Hazardous Substances Data: 118487-15-3(Hazardous Substances Data)

Upstream product

• 79999-47-6 tri-O-(tert-butyldimethylsilyl)-D-glucal 
• 882-33-7 diphenyldisulfane 

Relevant articles and documents

Preparation and Reactions of Some Cyclic Orthoester Derivatives

Deprotonation of the alkoxysulphone (5) followed by quenching with diphenyl disulphide yields the dithioorthoester (6) and not the expected ketene monothioacetal (7).Attempts at orthoester exchange of (6) with decanol with a variety of reagents lead to ring opened products.Quenching of the anion derived from (5) with sulphuryl chloride or bromine leads respectively to the chloride (19) and bromide (20).Solvolysis of these halides leads to formation of sulphinate esters.