1185733-88-3

Basic information

• Product Name: 2,2,2-trichloroethyl benzylsulfamate
• Synonyms: 2,2,2-trichloroethyl benzylsulfamate
• CAS NO: 1185733-88-3
• Molecular Weight: 318.608
• Mol File: 1185733-88-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2,2-trichloroethyl benzylsulfamate(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,2-trichloroethyl benzylsulfamate(1185733-88-3)
• EPA Substance Registry System: 2,2,2-trichloroethyl benzylsulfamate(1185733-88-3)

Safety Data

• Hazardous Substances Data: 1185733-88-3(Hazardous Substances Data)

Upstream product

• 69226-51-3 2,2,2-trichloroethyl sulfamate 
• 108-88-3 toluene 
• 1185733-70-3 2,2,2-trichloroethoxysulfuryl 2-methyl-3-methylimidazolium triflate 
• 100-46-9 benzylamine 

Relevant articles and documents

Introducing a mixed-valent dirhodium(ii,iii) catalyst with increased stability in C-H amination

A new mixed-valent Rh2II,III dimer, [Rh 2(espn)2Cl] (espn2- = α,α, α′,α′-tetramethyl-1,3-benzenedipropanamidate), is reported. This compound readily dissociates Cl- at low concentrations in solution to form the active [Rh2(espn)2]+ catalyst, which performs intramolecular C-H amination with TONs > 1400. This work expands the scope of Rh2II,III dimers to nitrenoid chemistry.

O- and N-sulfations of carbohydrates using sulfuryl imidazolium salts

(Chemical Equation Presented) A series of sulfuryl imidazolium salts (SISs) were prepared and examined as reagents for incorporating trichloroethyl- protected sulfate esters into carbohydrates. The SIS that contained a 1,2-dimethylimidazolium moiety (SIS