118575-53-4

Basic information

• Product Name: (5-methyl-2-furanyl)methyl 4-phenyl-3-butenoate
• Synonyms: (5-methyl-2-furanyl)methyl 4-phenyl-3-butenoate
• CAS NO: 118575-53-4
• Molecular Weight: 256.301
• Mol File: 118575-53-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (5-methyl-2-furanyl)methyl 4-phenyl-3-butenoate(CAS DataBase Reference)
• NIST Chemistry Reference: (5-methyl-2-furanyl)methyl 4-phenyl-3-butenoate(118575-53-4)
• EPA Substance Registry System: (5-methyl-2-furanyl)methyl 4-phenyl-3-butenoate(118575-53-4)

Safety Data

• Hazardous Substances Data: 118575-53-4(Hazardous Substances Data)

Upstream product

• 3857-25-8 2-hydroxymethyl-5-methylfuran 
• 118575-70-5 trans-styrylacetyl chloride 

Downstream Products

• 118575-69-2 4-(2-acetylethenyl)-3-(2-phenylethenyl)furan-2(5H)-one 
• 118575-71-6 4-(2-acetylethenyl)-3-(2-phenylethenyl)furan-2(5H)-one 
• 118575-62-5 (5-methyl-2-furanyl)methyl 2-diaza-4-phenyl-3-butenoate 

Relevant articles and documents

Scope and Stereochemistry of the Tandem Intramolecular Cyclopropanation/Cope Rearrangement Sequence

A stereoselective synthesis of a series of fused seven-membered carbocycles was achieved by a formal intramolecular 3 + 4 cycloaddition between vinylcarbenoids, generated by rhodium(II) acetate catalyzed decomposition of vinyldiazomethanes, and dienes.The products are formed by a tandem cyclopropanation/Cope rearrangement sequence rather than a concerted process.