1186296-19-4

Basic information

• Product Name: dimethyl (2R)-2-(4-chlorophenyl)-1,4-oxathiane-3,3-dicarboxylate
• CAS NO: 1186296-19-4
• Molecular Weight: 330.789
• Mol File: 1186296-19-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dimethyl (2R)-2-(4-chlorophenyl)-1,4-oxathiane-3,3-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl (2R)-2-(4-chlorophenyl)-1,4-oxathiane-3,3-dicarboxylate(1186296-19-4)
• EPA Substance Registry System: dimethyl (2R)-2-(4-chlorophenyl)-1,4-oxathiane-3,3-dicarboxylate(1186296-19-4)

Safety Data

• Hazardous Substances Data: 1186296-19-4(Hazardous Substances Data)

Upstream product

• 22391-05-5 2-(4-chlorophenyl)-1,3-oxathiolane 
• 6773-29-1 dimethyl diazomalonate 

Relevant articles and documents

Ligand-accelerated asymmetric [1,2]-Stevens rearrangment of sulfur ylides via decomposition of diazomalonates catalyzed by chiral bisoxazoline/copper complex

The first example of catalytic asymmetric [1,2]-Stevens rearrangement reaction of 1,3-oxathiolanes with diazomalonates has been developed and up to 90% ee is achieved by the bisoxazoline 4e/ copper(II) triflate [Cu(OTf) 2] complex.