1187030-79-0Relevant articles and documents
Synthesis, structure, photophysics, and a DFT study of phosphorescent C*N∥N- and C∥N∥N-coordinated platinum complexes
Harris, Caleb F.,Vezzu, Dileep A.K.,Bartolotti, Libero,Boyle, Paul D.,Huo, Shouquan
, p. 11711 - 11722 (2013)
The reaction of N,N-diphenyl-2,2′-bipyridin-6-amine (L1) and N,N-diphenyl-6-(1H-pyrazol-1-yl)pyridin-2-amine (L2) with K2PtCl 4 produced C*N∥N-coordinated cycloplatinated compounds with a five-six fused metallacycle 1a and
TRIDENTATE PLATINUM (II) COMPLEXES
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Page/Page column 23; 24, (2009/10/22)
A platinum (II) complex of the general formula (I) or (II), in which Ar1, Ar2, and Ar3 are each independently aryl, heteroaryl, or heterocyclic. Ar1, Ar2, and Ar3 together form a tridentate ligand coordinated to the platinum through atoms X, Y, and Z, respectively, and X, Y, and Z are independently carbon or nitrogen. V is a bridging group or a covalent bond, and W is an anion. In general formula (I) in some cases, Ar1 is an anion and Ar2 and Ar3 are neutral; in other cases, Ar1 and Ar3 are neutral and Ar2 is an anion. In general formula (II), in some cases, Ar3 is an anion and Ar1 and Ar2 are neutral; in other cases, Ar1 and Ar3 are neutral and Ar2 is an anion. The complexes are asymmetric. The complexes emit in the UV to near IR range and are useful as emitters for organic light emitting devices.