118712-58-6

Basic information

• Product Name: (2S)-glycidyl 2,4,5-trichlorobenzenesulfonate
• CAS NO: 118712-58-6
• Molecular Weight: 317.577
• Mol File: 118712-58-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S)-glycidyl 2,4,5-trichlorobenzenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: (2S)-glycidyl 2,4,5-trichlorobenzenesulfonate(118712-58-6)
• EPA Substance Registry System: (2S)-glycidyl 2,4,5-trichlorobenzenesulfonate(118712-58-6)

Safety Data

• Hazardous Substances Data: 118712-58-6(Hazardous Substances Data)

Upstream product

• 15945-07-0 2,4,5-trichlorobenzensulfonyl chloride 
• 60456-23-7 (S)-oxiranemethanol 

Relevant articles and documents

Arenesulfonate Derivatives of Homochiral Glycidol: Versatile Chiral Building Blocks for Organic Synthesis

The preparation of a series of crystalline arenesulfonate derivatives of enantiomerically enriched glycidol is described.The enhancement of optical purity by recrystallization was particularly successful for two of these derivatives, glycidyl tosylate and glycidyl 3-nitrobenzenesulfonate, which were obtained in 97 percent ee and 99 percent ee, respectively.Very high regioselectivity was observed in the reactions of these compounds with a variety of nucleophiles, including aryl oxides, Et2AlCN, organometallic reagents, and BH3-NaBH4.The application of this methodology to the synthesis of homochiral β-adrenergic blocking agents and homochiral terminal epoxides is discussed.