118795-49-6

Basic information

• Product Name: 1-Cyclohexylcarbamoyl-imidazolin-2-thion
• CAS NO: 118795-49-6
• Molecular Weight: 225.315
• Mol File: 118795-49-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Cyclohexylcarbamoyl-imidazolin-2-thion(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexylcarbamoyl-imidazolin-2-thion(118795-49-6)
• EPA Substance Registry System: 1-Cyclohexylcarbamoyl-imidazolin-2-thion(118795-49-6)

Safety Data

• Hazardous Substances Data: 118795-49-6(Hazardous Substances Data)

Upstream product

• 872-35-5 imidazole-2-thione 
• 3173-53-3 Cyclohexyl isocyanate 

Downstream Products

• 118795-50-9 2-Cyclohexyl-imidazo<1,2-d><1,2,4>thiadiazol-3(2H)-on 

Relevant articles and documents

Fission of 1,2,4-Thiadiazol-3-ones by Triphenylphosphane: Triphenylphosphonio Thioimidazolates and Their Consecutive Reactions

Treatment of benzimidazothiadiazol-3(2H)-ones (1) and imidazothiadiazol-3(2H)-ones (17) with triphenylphosphan leads to the liberation of isocyanate and the formation of triphenylphosphonio-thiobenzimidazolat (4) and triphenylphosphonio-thioimidazolat (18), respectively. 2,4-Diphenyl-5-phenylimino-1,2,4-thiadiazol-3-one (23) is desulfurized with Ph3P and decomposed into phenyl isocyanate and diphenylcarbodiimide whereas the N-unsubstituted imino-thiadiazol-3-one (25) is attacked at the exocyclic imino group by Ph3P to give the N-phosphoranylidene thiourea (26).The structure of 4 can be rationalized as a dynamic system between polar and apolar valence isomeres.Reactions of 1 and 17 with cyanates, isocyanates, carbon disulfide, acetic anhydride, amines, benzyl chloride, grignard compounds, and CH acidic compounds are described.