118847-62-4Relevant articles and documents
Catalytic asymmetric synthesis of dihydroquinazolinones from imines and 2-aminobenzamides
Cheng, Dao-Juan,Tian, Yu,Tian, Shi-Kai
supporting information; experimental part, p. 995 - 999 (2012/06/01)
An unprecedented catalytic asymmetric synthesis of aminal-containing heterocyclic compounds has been developed from imines and tethered nitrogen/nitrogen nucleophiles. In the presence of 10mol% of a commercially available chiral phosphoric acid, a range of aromatic, α,β- unsaturated, and aliphatic imines react with 2-aminobenzamides to give dihydroquinazolinones in good to excellent yields and ee. The enantioselectivity is significantly affected by the imine N-substituent through non-bonding interactions with the chiral phosphoric acid and the 2-aminobenzamide. Copyright
P′CP′-Pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines
Li, Jie,Minnaard, Adriaan J.,Klein Gebbink, Robertus J.M.,van Koten, Gerard
supporting information; experimental part, p. 2232 - 2235 (2009/07/26)
The P′CP′-pincer palladium complex-catalyzed allylation of N,N-dimethylsulfamoyl-protected aldimines with allyl(tributyl)stannane is investigated for the preparation of N-homoallylic sulfamides. The desired N,N-dimethylsulfamoyl-protected products are obt
