118852-20-3Relevant articles and documents
A bridging double bond as an electron acceptor for optical nonlinearity of furan-containing [n.2]cyclophenes
Lin, Hsin-Chieh,Lin, Wei-Yu,Bai, Hao-Tien,Chen, Jia-Hong,Jin, Bih-Yaw,Luh, Tien-Yau
, p. 897 - 900 (2007/10/03)
All in the twist: Unusually large Stokes shifts and nonlinear optical properties are exhibited by furan-containing teraryl cyclophene derivatives (see picture). These cyclophenes have neither particularly strong electron-donating nor electron-withdrawing
Paracyclophane-10-enes and Paracyclophane-10,27-dienes: A Convenient Synthesis by the McMurry Reaction and Dynamic Stereochemistry
Gruetzmacher, Hans-Friedrich,Neumann, Ekkehard,Ebmeyer, Frank,Albrecht, Karsten,Schelenz, Peter
, p. 2291 - 2298 (2007/10/02)
The 1,3-bis(4-acylphenyl)propanes 2, 3, 9, 12, and 15 were subjected to a cyclization by reductive coupling with low-valent titanium (McMurry reaction). 2 and 3 are converted into the corresponding 10,11-dialkylparacyclophane-10-enes 4 and 5, respect