1190764-14-7Relevant articles and documents
Development of new conjugated polymers with donor-π-bridge-acceptor side chains for high performance solar cells
Huang, Fei,Chen, Kung-Shih,Yip, Hin-Lap,Hau, Steven K.,Acton, Orb,Zhang, Yong,Luo, Jingdong,Jen, Alex K.-Y.
, p. 13886 - 13887 (2009)
(Graph Presented) Two new conjugated polymers have been designed and synthesized for polymer solar cells. Both of them exhibit excellent photovoltaic properties with a power conversion efficiency as high as 4.74%. Different from the traditional linear don
Poly (triphenylamine-fluorenylmethylchloroformate) dye and its application
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Paragraph 0127; 0129; 0130; 0131, (2017/02/28)
The invention discloses a poly(triphenylamine-fluorene) dye and its application. The poly(triphenylamine-fluorene) dye is prepared through a Stille coupling reaction of a monomer having a triphenylamine structure and a monomer having a fluorene structure. The prepared poly(triphenylamine-fluorene) dye has a triphenylamine and fluorene composite donor unit structure, and can be applied in the production of dye-sensitized solar cells in order to obtain dye-sensitized solar cells with high current density and high photoelectric conversion rate.
Fluorescent and colorimetric probes for mercury(II): Tunable structures of electron donor and π-conjugated bridge
Cheng, Xiaohong,Li, Shuang,Jia, Huizhen,Zhong, Aoshu,Zhong, Cheng,Feng, Jun,Qin, Jingui,Li, Zhen
body text, p. 1691 - 1699 (2012/03/27)
A new series of intramolecular-charge-transfer (ICT) molecules (compounds 1, 2, and 3) were synthesized by attaching various electron-donating thiophenes groups to a triphenylamine backbone with an aldehyde group as the electron acceptor. Based on the protection reaction between ethanethiol and aldehyde, the corresponding dithioacetals (compounds S1, S2, and S3) were prepared to serve as novel colorimetric and fluorescent chemosensors for Hg2+ ions. Also, compound S1 was further utilized to construct the chemical-reaction-based conjugated polymer probe (PS1) towards Hg2+ ions. In the presence of as little as 10 nM Hg2+, compound PS1 displayed an apparent change in the fluorescent intensity. The sensing processes were revealed to be mediated by ICT, as confirmed by time-dependent DFT calculations. Furthermore, compound S1 was successfully applied to microscopic imaging for the detection of Hg 2+ in HeLa cells with ratiometric fluorescent methods. Copyright