119116-56-2Relevant articles and documents
Correlation between conformational equilibria of free host and guest binding affinity in non-preorganized receptors
Carrillo, Romen,Morales, Ezequiel Q.,Martin, Victor S.,Martin, Tomas
, p. 7785 - 7795 (2013/09/12)
Positive cooperativity between host conformational equilibria and guest binding has been widely reported in protein receptors. However, reported examples of this kind of cooperativity in synthetic hosts are scarce and largely serendipitous, among other th
Simple designs for the construction of complex trans-fused polyether toxin frameworks. A convergent strategy based on hydroxy ketone cyclization of C-linked oxacycles
Alvarez, Eleuterio,Perez, Ricardo,Rico, Milagros,Rodriguez, Rosa M.,Martin, Julio D.
, p. 3003 - 3016 (2007/10/03)
A single, unified convergent strategy for the stereocontrolled synthesis of trans-fused polyethers was developed. It was demonstrated that the epimerization and reductive intramolecular coupling of hydroxy ketones in reactions with silane - Lewis acids (S
A CONVERGENT SYNTHESIS OF THE O-BENZYL DERIVATIVE OF ENANTIO-INEUPATORIOL FROM A CARBOHYDRATE PRECURSOR
Still, Ian W. J.,Banait, Narinder S.,Frazer, Donald V.
, p. 1461 - 1474 (2007/10/02)
The trans-2,3-disubstituted tetrahydropyran 7, obtained in eight steps from methyl α-D-glucoside, and the phosphonium salt 10, obtained from thiophene in six steps, were successfully combined in a Wittig reaction to form 11, the O-benzyl enantiomer of the
