119139-91-2Relevant articles and documents
DIASTEREOSELECTIVE SYNTHESIS OF HEXAHYDRO-3H-OXAZOLOPYRIDIN-3-ONE DERIVATIVES BY CYCLIZATION OF α-ACYLAMINORADICAL-OLEFIN SYSTEM
Kano, Shinzo,Yuasa, Yoko,Asami, Kenji,Shibuya, Shiroshi
, p. 1437 - 1444 (2007/10/02)
The substituent effect in α-acylaminoradical-olefin cyclization was examined.Treatment of 4-phenylthiooxazolidin-2-ones (10a-f) with tri-n-butyltin hydride in the presence of AIBN yielded 6,7-cis-6,8a-trans-6-alkyl-7-arylhexahydrooxazolopyridin-3-ones (11a-f), respectively, with high diastereoselectivity.