119139-93-4Relevant articles and documents
Palladium-Catalyzed Highly Regio- and Stereoselective Addition of Organoboronic Acids to Allenes in the Presence of AcOH
Ma, Shengming,Jiao, Ning,Ye, Longwu
, p. 6049 - 6056 (2003)
The Pd0-catalyzed regio- and stereoselective addition of organoboronic acids to allenes leads to stereodefined tri- or tetrasubstituted alkenes. Furthermore, this method shows high substitutent-loading capability and tolerance of various substitutents. A hydropalladation-Suzuki coupling mechanism, which may account for the regio- and stereoselectivity, is proposed.
Diastereoselective Intramolecular Hydride Transfer Triggered by Electrophilic Halogenation of Aryl Alkenes
Wang, Bin,Gandamana, Dhika Aditya,León Rayo, David Fabian,Gagosz, Fabien,Chiba, Shunsuke
supporting information, p. 9179 - 9182 (2019/11/14)
Diastereoselective hydride transfer could be triggered by electrophilic halogenation (bromination or fluorination) of homoallylic alcohol O-Bn ethers. The resulting diastereomerically enriched haloalkyl alcohols underwent subsequent intramolecular nucleop