119145-34-5Relevant articles and documents
Dipolar cycloaddition reaction of diazoalkanes with trimethylsilyl substituted alkynes. Steric control of regiochemistry by the trimethylsilyl group
Padwa, Albert,Wannamaker, M. Woods
, p. 1145 - 1162 (2007/10/02)
A study of the cycloaddition behavior of several trimethylsilyl substituted alkynes with 2-diazopropane and diazomethane has been carried out. Aryl or alkyl ethynyl sulfones react to give 5-sulfonyl substituted 3H-pyrazoles which extrude nitrogen on photo