1192023-27-0

Basic information

• Product Name: (E)-3-[2-{(E)-2-tert-butoxycarbonylvinyl}-4,5-difluorophenyl]acrylic acid tert-butyl ester
• Synonyms: (E)-3-[2-{(E)-2-tert-butoxycarbonylvinyl}-4,5-difluorophenyl]acrylic acid tert-butyl ester
• CAS NO: 1192023-27-0
• Molecular Weight: 366.405
• Mol File: 1192023-27-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-3-[2-{(E)-2-tert-butoxycarbonylvinyl}-4,5-difluorophenyl]acrylic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-[2-{(E)-2-tert-butoxycarbonylvinyl}-4,5-difluorophenyl]acrylic acid tert-butyl ester(1192023-27-0)
• EPA Substance Registry System: (E)-3-[2-{(E)-2-tert-butoxycarbonylvinyl}-4,5-difluorophenyl]acrylic acid tert-butyl ester(1192023-27-0)

Safety Data

• Hazardous Substances Data: 1192023-27-0(Hazardous Substances Data)

Upstream product

• 1663-39-4 tert-Butyl acrylate 
• 64695-78-9 1,2-difluoro-4,5-dibromobenzene 

Relevant articles and documents

Enantioselective copper-catalyzed reductive michael cyclizations

In the presence of siloxanes as stoichiometric reductants, chiral copper-bisphosphine complexes catalyze highly enantioselective reductive Michael cyclizations of substrates containing two α,β-unsaturated carbonyl moieties. The diastereochemical outcome of these reactions Is dependent upon whether biaryl- or ferrocene-based chiral bisphosphines are employed.