1192264-10-0Relevant articles and documents
Tuning diketodioxinone reactivity: Biomimetic synthesis of the resorcylate antibiotic fungal metabolites ent-W1278A, -B, and -C, using iterative aromatization reactions
Navarro, Ismael,Poeverlein, Christoph,Schlingmann, Gerhard,Barrett, Anthony G. M.
supporting information; experimental part, p. 8139 - 8142 (2010/03/01)
(Chemical Equation Presented) The onset temperature of the retro-Diels-Alder reactions of diketo-1,3-dioxin-2-ones to generate α,γ,ε-triketo-ketenes was found to be significantly reduced with 2-phenyl substitution. These ketenes, generated at 78°C, were t