119237-86-4

Basic information

• Product Name: allyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside
• Synonyms: allyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside
• CAS NO: 119237-86-4
• Molecular Weight: 488.58
• Mol File: 119237-86-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: allyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside(119237-86-4)
• EPA Substance Registry System: allyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside(119237-86-4)

Safety Data

• Hazardous Substances Data: 119237-86-4(Hazardous Substances Data)

Upstream product

• 7296-15-3 alpha-D-mannopyranoside 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 100-39-0 benzyl bromide 
• 81600-93-3 allyl 4,6-di-O-benzylidene-α-D-mannopyranoside 
• 4163-65-9 per-O-acetyl-α-D-mannopyranose 
• 214490-84-3 Allyl 2,3,4,6-Tetra-O-acetyl-D-mannopyranoside 
• 119111-33-0 (3aS,5aR,8R,9aR,9bS)-4-Allyloxy-2,8-diphenyl-hexahydro-[1,3]dioxolo[4',5':4,5]pyrano[3,2-d][1,3]dioxine 
• 618-31-5 benzylidene dibromide 
• 182212-07-3 α,β-O-allyl-D-mannopyranoside 
• 530-26-7 D-Mannose 
• 100-44-7 benzyl chloride 
• 1056479-53-8 allyl-4,6-O-benzylidene-2,3-di-O-hydroxy-D-mannopyranoside 
• 41308-76-3 allyl α-D-mannopyranoside 
• 3458-28-4 D-Mannose 

Downstream Products

• 154172-24-4 2,3-bis-O-(phenylmethyl)-4,6-O-[(R)-phenylmethylene]-α-D-mannopyranoside 
• 119237-94-4 <2R-(2α,4aβ,5α,6β,7β,7aβ)>-Hexahydro-5-methyl-2-phenyl-6,7-bis(phenylmethoxy)cyclopenta-1,3-dioxin 
• 119237-95-5 <2R-(2α,4aβ,5β,6β,7β,7aβ)>-Hexahydro-5-methyl-2-phenyl-6,7-bis(phenylmethoxy)cyclopenta-1,3-dioxin 
• 119237-93-3 (R)-1,2-Dideoxy-3,4-bis-O-(phenylmethyl)-5,7-O-(phenylmethylene)-D-manno-hept-1-enitol 
• 119111-10-3 Imidazole-1-carbothioic acid O-[(2R,4R,5R)-4-((1R,2R)-1,2-bis-benzyloxy-but-3-enyl)-2-phenyl-[1,3]dioxan-5-yl] ester 
• 95475-35-7 allyl 2,3,6-tri-O-benzyl-α-D-mannopyranoside 
• 912650-59-0 3,4,5,7-tetra-O-benzyl-1-deoxy-α-D-manno-hept-2-ulosyl-(2->4)-2,3,6-tri-O-benzyl-D-mannono-1,5-lactone 
• 912650-56-7 3,4,5,7-tetra-O-benzyl-1-deoxy-α-D-galacto-hept-2-ulosyl-(2->4)-2,3,6-tri-O-benzyl-D-mannono-1,5-lactone 
• 912650-53-4 3,4,5,7-tetra-O-benzyl-1-deoxy-α-D-gluco-hept-2-ulosyl-(2->4)-2,3,6-tri-O-benzyl-D-mannono-1,5-lactone 
• 912651-00-4 2,3,6-tri-O-benzyl-D-mannono-1,5-lactone 
• 20770-84-7 2,3-di-O-benzyl-4,6-O-benzylidene-α/β-D-mannopyranose 
• 154125-79-8 methyl β-xylopyranosyl-(1→4)-β-D-mannopyranoside 
• 154125-76-5 (2,3-di-O-benzyl-4,6-O-benzylidene-D-mannopyranosylidene)amino 2,4,6-trimethylbenzene-1-sulfonate 
• 154125-75-4 2,3-di-O-benzyl-4,6-O-benzylidene-D-mannonhydroximo-1,5-lactone 

Relevant articles and documents

Synthesis of the mannopeptimycin disaccharide and its conjugation with 4-alkylidene-β-lactams

The disaccharide moiety of the antibiotic mannopeptimycin has been synthesized as a (N-phenyl)trifluoroacetimidate donor, the reactivity of which was tested in conjugation with a 4-alkylidene-β-lactam acceptor. Key steps of the synthesis were Bi(OTf)

Efficient installation of β-mannosides using a dehydrative coupling strategy

(Chemical Equation Presented) A new coupling procedure for the construction of the challenging β-mannosidic bond is described. Dehydrative mannosylation using 4,6-O-benzylidene mannopyranoses allows for the formation of β-mannosides in excellent yield. Th

Glycosylidene carbenes. Part 13. Synthesis and thermolysis of representative 1-azi-glycoses

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