119273-51-7Relevant articles and documents
Aryl 1,5-dithia-2,4,6,8-tetrazocines. A synthetic, electrochemical, and structural investigation
Boere, Rene T.,Moock, Klaus H.,Derrick, Sean,Hoogerdijk, William,Preuss, Kathryn,et al.
, p. 473 - 486 (2007/10/02)
New preparative routes to the title compounds are reported in which the yields are substantially improved over previous methods.In one method, reaction of O2 with a mixture of XC6H4CN2S2(+)*Cl(-) and Ph3Sb leads to the products in 40-60percent yield.In an
Preparation of Dithiatetrazocines and Secondary Reactions
Scholz, Uwe,Roesky, Herbert W.,Schimkowiak, Juergen,Noltemeyer, Mathias
, p. 1067 - 1070 (2007/10/02)
Li (1) or PhCN2(SiMe3)3 (3) react with SCl2 to give in good yields the dithiatetrazocine PhC(NSN)2CPh (2).By analogy, p-MeC6H4C(NSN)2CC6H4Me-p (7), p-NO2C6H4C(NSN)2CC6H4NO2-p (8), and p-CF3C6H4C(NSN)2CC6H4CF3-p (9) are obtained from the rea