119301-59-6

Basic information

• Product Name: Phenol, 4,4',4'',4'''-(1,2-ethenediylidene)tetrakis-
• Synonyms: Phenol, 4,4',4'',4'''-(1,2-ethenediylidene)tetrakis-;Tetrakis(4-hydroxyphenyl)ethene;Tetrakis(4-hydroxyphenyl)ethylene;tetrakis(4-hydroxytetraphenyl)ethene;4,4',4'',4'''-(Ethene-1,1,2,2-tetrayl)tetraphenol;Tetrakis(4-hydroxyphenyl)ethane;4,4',4'',4'''-(1,1,2,2-Ethenetetrayl)tetraphenol
• CAS NO: 119301-59-6
• Molecular Formula: C₂₆H₂₀O₄
• Molecular Weight: 396.4346
• Mol File: 119301-59-6.mol
• Article Data: 37

Chemical Properties

• Melting Point: 323°C(lit.)
• Boiling Point: 559.4±45.0 °C(Predicted)
• Appearance: /
• Density: 1.324±0.06 g/cm3(Predicted)
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• PKA: 9.72±0.26(Predicted)
• CAS DataBase Reference: Phenol, 4,4',4'',4'''-(1,2-ethenediylidene)tetrakis-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 4,4',4'',4'''-(1,2-ethenediylidene)tetrakis-(119301-59-6)
• EPA Substance Registry System: Phenol, 4,4',4'',4'''-(1,2-ethenediylidene)tetrakis-(119301-59-6)

Safety Data

• Hazardous Substances Data: 119301-59-6(Hazardous Substances Data)

Usage

Description

Phenol, 4,4',4'',4'''-(1,2-ethenediylidene)tetrakis-, also known as TPE-TOH, is a synthetic intermediate with a complex chemical structure. It is characterized by its ability to form aggregation-induced emission (AIE) dyes, which are of significant interest in the field of materials science and chemistry due to their unique optical properties.

Uses

Used in Chemical Synthesis:
Phenol, 4,4',4'',4'''-(1,2-ethenediylidene)tetrakisis used as a synthetic intermediate for the production of aggregation-induced emission (AIE) dyes. Its application is crucial in the further synthesis of alkyl-halogen to make ether via esterification and polymer reaction, which contributes to the development of new materials with enhanced properties and potential applications in various industries.
Used in Optoelectronic Applications:
In the optoelectronic industry, Phenol, 4,4',4'',4'''-(1,2-ethenediylidene)tetrakisis used as a key component in the development of AIE dyes. These dyes exhibit enhanced fluorescence in the aggregated state, making them suitable for applications such as organic light-emitting diodes (OLEDs), sensors, and bioimaging.
Used in Pharmaceutical Research:
Phenol, 4,4',4'',4'''-(1,2-ethenediylidene)tetrakismay also find applications in the pharmaceutical industry, particularly in the development of new drugs and drug delivery systems. The unique properties of AIE dyes, such as their fluorescence enhancement in aggregated states, can be exploited for targeted drug delivery and imaging of biological processes.

Upstream product

• 10019-24-6 1,1,2,2-tetrakis(4-methoxyphenyl)ethene 
• 119-61-9 benzophenone 
• 611-99-4 4,4'-Dihydroxybenzophenone 
• 17435-03-9 dichloro-bis-(4-methoxy-phenyl)-methane 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 90-96-0 bis(p-methoxyphenyl)methanone 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 123-11-5 4-methoxy-benzaldehyde 
• 728-87-0 4,4'-Dimethoxybenzhydrol 
• 108-95-2 phenol 
• 99-96-7 4-hydroxy-benzoic acid 

Downstream Products

• 1166400-22-1 tetrakis{4-[(2S)-benzyloxypropyl]phenyl}ethene 
• 1166400-23-2 tetrakis{4-[(2S)-methoxymethoxypropyl]phenyl}ethene 
• 1166400-13-0 tetrakis{4-[(2S)-methoxypropionate]phenyl}ethene 
• 1166400-14-1 tetrakis{4-[(2S)-ethoxypropionate]phenyl}ethene 
• 1166400-04-9 tetrakis-{4-[(3'R)-3',7'-dimethyloct-6'enyloxy]phenyl}ethene 
• 1166400-15-2 tetrakis{4-[(2S)-propyloxypropionate]phenyl}ethene 
• 1166400-19-6 tetrakis{4-[(2S)-benzyloxypropionate]phenyl}ethene 
• 1166400-18-5 tetrakis{4-[(2S)-decyloxypropionate]phenyl}ethene 
• 1166400-16-3 tetrakis{4-[(2S)-pentyloxypropionate]phenyl}ethene 
• 1166400-17-4 tetrakis{4-[(2S)-octyloxypropionate]phenyl}ethene 
• 1227474-61-4 1,1,2,2-tetrakis-[4-(prop-2-ynyloxy)phenyl]ethylene 
• 1306201-17-1 tetraethyl 2,2′,2″,2?-((ethane-1,1,2,2-tetrakis(benzene-4,1-diyl)))tetrakis-(oxy)tetraacetate 
• 1367245-78-0 C₅₀H₆₀O₁₂ 
• 1355393-58-6 C₅₄H₃₂Br₄O₈ 

Relevant articles and documents

A supramolecular fluorescent vesicle based on a coordinating aggregation induced emission amphiphile: Insight into the role of electrical charge in cancer cell division

Binding of Zn2+ to the coordinating supramolecular vesicle based on an aggregation induced emission amphiphile TPE-BPA immediately triggers the formation of charged vesicles. This induces vesicle fission and fluorescence reduction, suggesting a

Recyclable Supramolecular Assembly-Induced Emission System for Selective Detection and Efficient Removal of Mercury(II)

An efficient strategy for simultaneously detecting and removing Hg2+ from water is vital to address mercury pollution. Herein a supramolecular assembly G?H with photoluminescent properties is facilely constructed through the self-assembly of a

A new strategy to access polymers with aggregation-induced emission characteristics

A highly efficient strategy for synthesizing the first biocompatible polyesters with AIE characteristics has been established via immortal ring-opening polymerizations of cyclic esters bearing nonluminophores. In the process, the large excess hydroxyl-mod

Circularly polarized luminescence based on columnar self-assembly of tetraphenylethylene with multiple cholesterol units

The influence of different states of AIE derivative with columnar liquid crystalline phase on circularly polarized luminescence (CPL) was investigated in this work. Two novel tetraphenylethylene derivatives with multiple cholesterol units (TPE-C and TPE-SC) were prepared. They exhibited enantiotropic liquid crystalline behaviours with the ordered hexagonal columnar mesophase. They possessed excellent AIE properties in H2O-THF system. The fluorescence quantum yields of TPE-C and TPE-SC at solid state were as high as 28.8% and 22.6%, respectively. The chiral transfer from cholesterol units to TPE cores was confirmed by CD spectra. The studies on CPL spectra suggested that their CPL behaviors were tuned by the different states. They showed weak CPL properties at solid and isotropic state but strong CPL luminescence at liquid crystalline phase based on the orderly columnar self-assembly. The glum of TPE-SC at liquid crystalline phase reached 8.83 × 10?2.

Light and reduction responsive supra-amphiphile for controllable fluorescence based on Pillar[6]arene

As increasing demands of smart fluorescent materials, developing new systems with controllable emissions is more essential. Here we report a pillar[6]arene and tetraphenylethene (TPE)-based supra-amphiphile, which shows dual-responsiveness and tunable emi