119327-32-1

Basic information

• Product Name: Silane, [2-(4-methoxyphenyl)ethenyl]trimethyl-, (Z)-
• CAS NO: 119327-32-1
• Molecular Formula: C12H18OSi
• Molecular Weight: 206.36
• Mol File: 119327-32-1.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Silane, [2-(4-methoxyphenyl)ethenyl]trimethyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [2-(4-methoxyphenyl)ethenyl]trimethyl-, (Z)-(119327-32-1)
• EPA Substance Registry System: Silane, [2-(4-methoxyphenyl)ethenyl]trimethyl-, (Z)-(119327-32-1)

Safety Data

• Hazardous Substances Data: 119327-32-1(Hazardous Substances Data)

Upstream product

• 696-62-8 para-iodoanisole 
• 754-05-2 ethenyltrimethylsilane 
• 5926-35-2 chlorobis(trimethylsilyl)methane 
• 123-11-5 4-methoxy-benzaldehyde 
• 138351-84-5 1-(4-methoxyphenyl)-2-trimethylsilylethanol 
• 3989-14-8 (4-methoxyphenylethynyl)trimethylsilane 
• 617-86-7 triethylsilane 
• 768-60-5 4-methoxyphenylacetylen 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 41309-43-7 (2-bromovinyl)trimethylsilane 
• 336193-48-7 2-chloro-1-(4-methoxy-phenyl)-2-trimethylsilanyl-ethanol 
• 1068-69-5 Tris(trimethylsilyl)methane 
• 18178-59-1 (E)-1,2-bis(trimethylsilyl)ethene 

Downstream Products

• 22255-22-7 3,5,4'-trimethoxy-trans-stilbene 
• 501-36-0 (E)-5-[2-4-(hydroxyphenyl)ethenyl]-1,3-benzenediol 
• 5043-91-4 (E)-4-chloro-4'-methoxystilbene 
• 247217-74-9 3-acetoxy-1-(4-methoxyphenyl)-2-trimethylsilylpropene 
• 26306-99-0 2-methyl-3-(4-methoxyphenyl)cyclopropenone 

Relevant articles and documents

Nickel-Catalyzed Enantioselective α-Alkenylation of N-Sulfonyl Amines: Modular Access to Chiral α-Branched Amines

Chiral α-branched amines are common structural motifs in functional materials, pharmaceuticals, and chiral catalysts. Therefore, developing efficient methods for preparing compounds with these privileged scaffolds is an important endeavor in synthetic chemistry. Herein, we describe an atom-economical, modular method for a nickel-catalyzed enantioselective α-Alkenylation of readily available linear N-sulfonyl amines with alkynes to afford a wide variety of allylic amines without the need for exogenous oxidants, reductants, or activating reagents. The method provides a platform for constructing chiral α-branched amines as well as derivatives such as α-Amino amides and β-Amino alcohols, which can be conveniently accessed from the newly introduced alkene. Given the generality, versatility, and high atom economy of this method, we anticipate that it will have broad synthetic utility.

Iron-Catalyzed Cross-Coupling of Bis-(aryl)manganese Nucleophiles with Alkenyl Halides: Optimization and mechanistic investigations

Various substituted bis-(aryl)manganese species were prepared from aryl bromides by one-pot insertion of magnesium turnings in the presence of LiCl and in situ trans-metalation with MnCl2 in THF at ?5 ?C within 2 h. These bis-(aryl)manganese reagents undergo smooth iron-catalyzed cross-couplings using 10 mol% Fe(acac)3 with various functionalized alkenyl iodides and bromides in 1 h at 25 ?C. The aryl-alkenyl cross-coupling reaction mechanism was thoroughly investigated through paramagnetic 1H-NMR, which identified the key role of tris-coordinated ate-iron(II) species in the catalytic process.

Rapid and efficient entry to vinyl silanes from aldehydes employing a novel metalation-Peterson sequence

Bis(trimethylsilyl)chloromethane undergoes a rapid and selective metalation with s-BuLi, yielding the nucleophilic bis(trimethylsilyl)methyl anion and providing a straightforward general entry to vinyl silanes from aromatic, aliphatic and vinyl aldehydes. The Royal Society of Chemistry.