119392-35-7Relevant articles and documents
GLYCALS IN STEREOSPECIFIC SYNTHESIS. II. DI-O-BENZYL-L-ARABINAL AND DI-O-BENZOYL-L-ARABINAL IN THE SYNTHESIS OF SATURATED AND UNSATURATED TERMINAL EPOXIDES
Tolstikov, A. G.,Khakhalina, N. V.,Savateeva, E. E.,Spirikhin, L. V.,Odinokov, V. N.,Tolstikov, G. A.
, p. 706 - 710 (2007/10/02)
The acid opening of di-O-benzyl-L-arabinal and di-O-benzoyl-L-arabinal, catalyzed by mercuric sulfate, is the key stage in the synthesis of chiral dihydroxy compounds with selectively protected hydroxy functions.They were used for the production of saturated and unsaturated terminal epoxides, which are of potential interest as chiral units in the convergent synthesis of biologically active compounds.
