119392-86-8

Basic information

• Product Name: N-acetyl-2-benzylaminobenzonitrile
• Synonyms: N-acetyl-2-benzylaminobenzonitrile
• CAS NO: 119392-86-8
• Molecular Weight: 250.3
• Mol File: 119392-86-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-acetyl-2-benzylaminobenzonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: N-acetyl-2-benzylaminobenzonitrile(119392-86-8)
• EPA Substance Registry System: N-acetyl-2-benzylaminobenzonitrile(119392-86-8)

Safety Data

• Hazardous Substances Data: 119392-86-8(Hazardous Substances Data)

Upstream product

• 5589-62-8 2-(benzylamino)benzonitrile 
• 108-24-7 acetic anhydride 

Downstream Products

• 1040073-83-3 C₁₆H₁₆N₂ 
• 3440-46-8 4-amino-2-methylquinazoline 
• 119392-89-1 1-benzyl-2-methyl-4(1H)-quinazolone 
• 82216-70-4 3-(2-benzylaminophenyl)-5-methyl-1,2,4-oxadiazole 
• 119392-83-5 1-benzyl-2-methyl-4(1H)-quinazolone oxime 

Relevant articles and documents

Ring Transformation of 1,2-Disubstituted 4(1H)-Quinazolone Oximes to 3,5-Disubstituted 1,2,4-Oxadiazoles

In basic media O-benzoyl- and O-acetyl-2-benzylaminobenzamide oxime (8b, c) give 5-substituted 3-(2-benzylaminophenyl)-1,2,4-oxadiazoles (9a, b), while on heating in pure water 2-amino-1-benzylbenzimidazole (10) is formed.Reaction of 2-(N-acylbenzylamino)benzonitrile (12) with hydroxylamine, or treatment of O-acyl-2-(N-benzoylbenzylamino)benzamide oximes (8f, g) with acid give the novel 1,2-disubstituted 4(1H)-quinazolone oximes 13, which isomerize on heating with alkali by an ANRORC mechanism to the 1,2,4-oxadiazoles 9a, b. - Keywords: ANRORC mechanism; 1,2,4-Oxadiazoles; 4(1H)-Quinazolone oximes