119433-11-3

Basic information

• Product Name: (1R,2R,3R,5R,8R)-(+)-8-Benzoyloxy-2,7,7-trimethylbicyclo<3.3.0>octan-3-ol
• Synonyms: (1R,2R,3R,5R,8R)-(+)-8-Benzoyloxy-2,7,7-trimethylbicyclo<3.3.0>octan-3-ol
• CAS NO: 119433-11-3
• Molecular Weight: 288.387
• Mol File: 119433-11-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1R,2R,3R,5R,8R)-(+)-8-Benzoyloxy-2,7,7-trimethylbicyclo<3.3.0>octan-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,3R,5R,8R)-(+)-8-Benzoyloxy-2,7,7-trimethylbicyclo<3.3.0>octan-3-ol(119433-11-3)
• EPA Substance Registry System: (1R,2R,3R,5R,8R)-(+)-8-Benzoyloxy-2,7,7-trimethylbicyclo<3.3.0>octan-3-ol(119433-11-3)

Safety Data

• Hazardous Substances Data: 119433-11-3(Hazardous Substances Data)

Upstream product

• 90546-12-6 (3aRS,6RS,6aRS)-6-benzoyloxy-3,3a,4,5,6,6a-hexahydro-1,5,5-trimethylpentalene 
• 69478-30-4 (3aRS,6SR,6aRS)-3,3a,4,5,6,6a-hexahydro-6-hydroxy-1,5,5-trimethylpentalene 
• 69478-30-4 (1R,3aS,6aR)-2,2,6-Trimethyl-1,2,3,3a,4,6a-hexahydro-pentalen-1-ol 
• 69478-28-0 (1R,3aR,6aS)-6-Hydroxymethyl-2,2-dimethyl-1,2,3,3a,4,6a-hexahydro-pentalen-1-ol 
• 90546-11-5 (3aRS,6SR,6aRS)-1-chloromethyl-3,3a,4,5,6,6a-hexahydro-6-hydroxy-5,5-dimethylpentalene 
• 82873-78-7 (3aRS,6SR,6aRS)-3,3a,4,5,6,6a-hexahydro-6-methanesulfonyloxy-1,5,5-trimethylpentalene 
• 90546-09-1 cis-3,3a,4,5,6,6a-hexahydro-5,5-dimethyl-6-oxo-1-pentalenecarboxylic acid methyl ester 
• 82873-74-3 (2aSR,4RS,4aSR,6aSR,6bRS)-octahydro-6,6-dimethyl-2-oxo-2H-pentaleno<1,6-bc>furan-4-carboxylic acid 
• 119337-76-7 (1R,3aR,5R,6R,6aR)-2,2,6-Trimethyl-5-(tetrahydro-pyran-2-yloxy)-octahydro-pentalen-1-ol 
• 119337-66-5 (1R,2S,6R,9R)-2-Methyl-3-oxabocyclo<4.3.0>nonan-9-ol 
• 119337-63-2 (6R,7R)-7-(tert-Butyldiphenylsilyloxy)-3-oxabicyclo<4.3.0>non-1-en-9-on 
• 119337-73-4 tert-Butyl-dimethyl-[(1R,3aR,5R,6R,6aR)-6-methyl-5-(tetrahydro-pyran-2-yloxy)-octahydro-pentalen-1-yloxy]-silane 
• 119337-83-6 tert-Butyl-dimethyl-((4aR,7R,7aS)-1-methyl-2-oxo-octahydro-2λ⁴-cyclopenta[c]thiopyran-7-yloxy)-silane 
• 119337-68-7 (1R,2S,6R,9R)-(-)-9-(tert-Butyldimethylsilyloxy)-2-methyl-3-oxabicyclo<4.3.0>nonan-4-on 

Downstream Products

• 80677-96-9 (-)-Hypnophilin 
• 127001-14-3 (3aS,3bR,4R,6aS)-(-)-6-(Benzoyloxy)-3,3a,3b,4,5,6,6a,7-octahydro-3a,5,5-trimethyl-2H-cyclopentapentalen-2-on 
• 127060-83-7 (1S,3aR,6R,6aR)-(+)-6-(Benzoyloxy)-1-(2-chlor-2-propenyl)-3,3a,4,5,6,6a-hexahydro-1,5,5-trimethyl-2(1H)-pentalenon 
• 127060-84-8 (1S,3aR,6R,6aR)-(-)-6-Benzoyloxy-3,3a,4,5,6,6a-hexahydro-1,5,5-trimethyl-1-(2-oxopropyl)-2(1H)-pentalenon 
• 85031-56-7 (3aR,3bS,4S,6aR,7R)-3,3a,5,5-Tetramethyl-3-phenylselanyl-4,7-bis-(tetrahydro-pyran-2-yloxy)-3,3a,3b,4,5,6,6a,7-octahydro-cyclopenta[a]pentalen-2-one 
• 82873-82-3 (1SR,3aRS,6RS,6aRS)-1-acetonyl-6-benzoyloxy-1,3a,4,5,6,6a-hexahydro-1,5,5-trimethyl-2(3H)-pentalenone 
• 82873-81-2 (1SR,3aRS,6RS,6aRS)-6-benzoyloxy-1-(2-chloro-2-propenyl)-1,3a,4,5,6,6a-hexahydro-1,5,5-trimethyl-2(3H)-pentalenone 
• 82881-09-2 6α-benzoyloxy-4β,7,7-trimethyl-1α,5α-bicyclo<3.3.0>octan-3-one 
• 127060-82-6 (1R,3aR,6R,6aR)-(+)-6-(Benzoyloxy)-3,3a,4,5,6,6a-hexahydro-1,5,5-trimethyl-2(1H)-pentalenon 

Relevant articles and documents

Chemistry and Stereochemistry of Iridoids, XVI. - EPC-Synthesis of (-)-Hypnophilin

The synthesis of enantiomerically pure (-)-hypnophilin (27) from (6R,7R)-(-)-7-hydroxy-3-oxabicyclonon-1-en-9-one (1) is described. 1 was obtained in 93 percent yield from catalpol, which is readily available from the aqueous sodium carbonate extra

SYNTHESIS OF dl-CORIOLIN

The total synthesis of dl-coriolin has been achieved in a stereoselective way.The key tricyclic intermediate was synthesized from dicyclopentadiene through a route which involved an SN2 reaction at a neopentylic position.