1196508-38-9

Basic information

• Product Name: 1,3-dicyclohexylpropa-1,2-diene
• Synonyms: 1,3-dicyclohexylpropa-1,2-diene
• CAS NO: 1196508-38-9
• Molecular Weight: 204.356
• Mol File: 1196508-38-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-dicyclohexylpropa-1,2-diene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-dicyclohexylpropa-1,2-diene(1196508-38-9)
• EPA Substance Registry System: 1,3-dicyclohexylpropa-1,2-diene(1196508-38-9)

Safety Data

• Hazardous Substances Data: 1196508-38-9(Hazardous Substances Data)

Upstream product

• 97563-45-6 1-cyclohexylprop-2-yn-1-ol 
• 1196508-28-7 (S)-1,3-dicyclohexylprop-2-ynyl methyl carbonate 
• 1220698-73-6 1,3-dicyclohexyl-2-propynyl formate 
• 1196508-18-5 1,3-dicyclohexylprop-2-ynyl methyl carbonate 
• 108-85-0 1-bromocyclohexane 
• 108104-21-8 1-cyclohexylprop-2-yn-1-yl acetate 
• 2043-61-0 cyclohexanecarbaldehyde 

Relevant articles and documents

Rhodium-Catalyzed Parallel Kinetic Resolution of Racemic Internal Allenes Towards Enantiopure Allylic 1,3-Diketones

A rare case of a parallel kinetic resolution of racemic 1,3-disubstituted allenes by means of a rhodium-catalyzed addition to 1,3-diketones furnishing enantiopure allylic 1,3-diketones is described. Mechanistic experiments demonstrate that the different allene enantiomers react in parallel to either the diastereomeric E- or Z-allylic 1,3-diketones with the same absolute configuration of the newly formed stereogenic center. A broad substrate scope demonstrates the synthetic utility of this new method.

Selective synthesis of allenes and alkynes through ligand-controlled, palladium-catalyzed decarboxylative hydrogenolysis of propargylic formates

Ligand-controlled regioselective palladium-catalyzed decarboxylative hydrogenolysis of propargylic formates is described. A wide range of allenes and alkynes were obtained by using either 1,2-diphenylphosphinoethane (DPPE) or 1,6-bisdiphenylphosphinohexane (DPPH) as a catalyst ligand.