1197333-07-5Relevant articles and documents
A new synthesis of β,γ-unsaturated esters and allenic esters with construction of a carbon-carbon bond between α- and β-positions by the reaction of magnesium alkylidene carbenoids with lithium ester enolates
Satoh, Tsuyoshi,Kaneta, Hiroaki,Matsushima, Ayako,Yajima, Masanobu
experimental part, p. 6280 - 6285 (2010/01/18)
Treatment of lithium ester enolates with magnesium alkylidene carbenoids, generated from 1-chlorovinyl p-tolyl sulfoxides with isopropylmagnesium chloride via the sulfoxide-magnesium exchange reaction, gave β,γ-unsaturated esters in moderate to good yield