119765-86-5Relevant articles and documents
First enantioselective total syntheses and absolute configurations of 4,5-dioxo-seco-γ-eudesmol and 5β,11-dihydroxyiphionan-4-one, two aglycones of naturally occurring sesquiterpenes with new skeletons
Gao,Xiong,Zhou,Li
, p. 37 - 39 (2007/10/03)
A facile synthetic route to two new carbon skeleton sesquiterpenes 4,5-dioxo-seco-γ-eudesmol and 5β,11-dihydroxyiphionan-4-one from (+)-dihydrocarvone has been described. The configuration of the 5β,11-dihydroxyipbionan-4-one was confirmed by stereospecific synthesis.