119784-71-3

Basic information

• Product Name: 5-<(E)-3,7-dimethyl-2,6-octadienylthio>-1-phenyl-1H-tetrazole
• Synonyms: 5-<(E)-3,7-dimethyl-2,6-octadienylthio>-1-phenyl-1H-tetrazole
• CAS NO: 119784-71-3
• Molecular Weight: 314.454
• Mol File: 119784-71-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-<(E)-3,7-dimethyl-2,6-octadienylthio>-1-phenyl-1H-tetrazole(CAS DataBase Reference)
• NIST Chemistry Reference: 5-<(E)-3,7-dimethyl-2,6-octadienylthio>-1-phenyl-1H-tetrazole(119784-71-3)
• EPA Substance Registry System: 5-<(E)-3,7-dimethyl-2,6-octadienylthio>-1-phenyl-1H-tetrazole(119784-71-3)

Safety Data

• Hazardous Substances Data: 119784-71-3(Hazardous Substances Data)

Upstream product

• 106-24-1 Geraniol 
• 51479-75-5 geranyl 2,2,2-trichloroacetimidate 
• 86-93-1 1-Phenyl-1H-tetrazole-5-thiol 
• 32276-00-9 S,S-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate 

Downstream Products

• 21488-83-5 (2E)-1-phenyl-3,7-dimethyl-2,6-octadiene 
• 72863-23-1 3,7-dimethyl-3-(p-tolylsulfonyl)-1,6-octadiene 
• 83110-46-7 3,7-dimethyl-1-(p-tolylsulfonyl)-2,6-octadiene 
• 60729-60-4 methyl (E)-2-benzenesulfonyl-5,9-dimethyl-4,8-decadienoate 

Relevant articles and documents

Alkylation of thiols with trichloroacetimidates under neutral conditions

Trichloroacetimidates are displaced with thiols to form the corresponding sulfides without the need for an added acid or base by simply heating the reactants in refluxing THF. This operationally simple procedure provides the corresponding sulfides in excellent yields with only the formation of the neutral trichloroacetamide as the side product. The imidate may also be formed in situ, allowing for a direct method for the formation of sulfides from alcohols. This reaction provides a general method for the synthesis of a variety of sulfides from inexpensive and readily available alcohol starting materials.

SINGLE-STEP PREPARATION OF ALLYLIC SULFIDES HAVING 1-PHENYLTETRAZOLE-5-THIO GROUP FROM ALLYLIC ALCOHOLS USING S,S'-BIS(1-PHENYL-1H-TETRAZOL-5-YL) DITHIOCARBONATE AND REACTIONS INVOLVING THE ALLYLIC SULFIDES

The reaction of allylic alcohols and S,S'-bis(1-phenyl-1H-tetrazol-5-yl) dithiocarbonate (1) gave allylic sulfides having 1-phenyltetrazole-5-thio group in a single step.Furthermore, these allylic sulfides could be applied to carbon-carbon bond and carbon-sulfur bond formations by using Grignard reagents or carbanions in the presence of catalytic amount of copper(I) bromide or palladium (0), respectively.