1198356-02-3

Basic information

• Product Name: (R)-benzyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butanoate
• Synonyms: (R)-benzyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butanoate
• CAS NO: 1198356-02-3
• Molecular Weight: 304.194
• Mol File: 1198356-02-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-benzyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-benzyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butanoate(1198356-02-3)
• EPA Substance Registry System: (R)-benzyl 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butanoate(1198356-02-3)

Safety Data

• Hazardous Substances Data: 1198356-02-3(Hazardous Substances Data)

Upstream product

• 71338-71-1 benzyl crotonate 
• 73183-34-3 bis(pinacol)diborane 
• 71338-71-1 benzyl (E)-2-butenoate 

Downstream Products

• 88280-53-9 (R)-3-hydroxybutanoic benzyl ester 

Relevant articles and documents

Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium-bisoxazolinylphenyl catalysts

Chiral rhodium-bisoxazolinylphenyl acetate complexes exhibited high catalytic activity for the β-boration of α,β-unsaturated carbonyl compounds with bis(pinacolato)diboron in the presence of sodium t-butoxide with enantioselectivity up to 97%.

Asymmetric β-boration of α,β-unsaturated carbonyl compounds with chiral Rh[bis(oxazolinyl)phenyl] catalysts

Chiral rhodium[bis(oxazolinyl)phenyl] complexes exhibited high catalytic activity for the β-boration of α,β-unsaturated esters, ketones, and amides with bis(pinacolato)diboron in the presence of sodium tert-butoxide to attain high enantioselectivity of up to 97%. The substrate scope and catalytic mechanism were discussed.