120123-60-6

Basic information

• Product Name: (2S,3S,4R,5S,6R)-4-Acetoxy-5-acetylamino-3-phenylsulfanyl-6-((1S,2R)-1,2,3-triacetoxy-propyl)-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester
• Synonyms: (2S,3S,4R,5S,6R)-4-Acetoxy-5-acetylamino-3-phenylsulfanyl-6-((1S,2R)-1,2,3-triacetoxy-propyl)-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester
• CAS NO: 120123-60-6
• Molecular Weight: 1046.16
• Mol File: 120123-60-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3S,4R,5S,6R)-4-Acetoxy-5-acetylamino-3-phenylsulfanyl-6-((1S,2R)-1,2,3-triacetoxy-propyl)-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,4R,5S,6R)-4-Acetoxy-5-acetylamino-3-phenylsulfanyl-6-((1S,2R)-1,2,3-triacetoxy-propyl)-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester(120123-60-6)
• EPA Substance Registry System: (2S,3S,4R,5S,6R)-4-Acetoxy-5-acetylamino-3-phenylsulfanyl-6-((1S,2R)-1,2,3-triacetoxy-propyl)-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester(120123-60-6)

Safety Data

• Hazardous Substances Data: 120123-60-6(Hazardous Substances Data)

Upstream product

• 73960-72-2 methyl-2,3-didehydro-4,7,8,9-tetra-O-acetyl-N-acetylneuraminate 
• 931-59-9 benzenesulfenyl chloride 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 120104-58-7 (3S,4R,5S,6R)-4-Acetoxy-5-acetylamino-2-chloro-3-phenylsulfanyl-6-((1S,2R)-1,2,3-triacetoxy-propyl)-tetrahydro-pyran-2-carboxylic acid methyl ester 

Downstream Products

• 109681-25-6 methyl O--(2->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside 

Relevant articles and documents

Efficient Synthesis of 2α-Glycoside od N-Acetylneuraminic Acid via Phenylsulfenyl Chloride Adduct of 2-Deoxy-2,3-dehydro-N-acetylneuraminic Acid Methyl Ester Tetra-O-acetate

Phenylsulfenyl chloride adds to a 2-deoxy-2,3-dehydro-N-acetylneuraminic acid derivative to give predominantly the corresponding 2-chloro-3β-phenylthio derivative, which is an excellent glycosyl donor for the preparation of α-glycosides of sialic acid.