1201762-98-2

Basic information

• Product Name: C₆H₁₀N₃⁽¹⁺⁾*C₉H₁₁O₃S^(1-)
• CAS NO: 1201762-98-2
• Molecular Weight: 323.416
• Mol File: 1201762-98-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₆H₁₀N₃⁽¹⁺⁾*C₉H₁₁O₃S^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₆H₁₀N₃⁽¹⁺⁾*C₉H₁₁O₃S^(1-)(1201762-98-2)
• EPA Substance Registry System: C₆H₁₀N₃⁽¹⁺⁾*C₉H₁₁O₃S^(1-)(1201762-98-2)

Safety Data

• Hazardous Substances Data: 1201762-98-2(Hazardous Substances Data)

Upstream product

• 13925-00-3 2-ethylpyrazine 
• 36016-40-7 mesitylenesulfonylhydroxylamine 

Relevant articles and documents

Regioselectivity in the amination of azines: Reaction of pyrazine derivatives with O-mesitylenesulfonylhydroxylamine

Treatment of 2-X-substituted pyrazines [X = H, Me, Et, Pr, i-Pr, t-Bu, MeCH(OH), H2N, AcNH] with O-mesitylenesulfonylhydroxylamine gave the corresponding 2-X- and 3-X-(1-amino)pyrazin-1-ium mesitylenesulfonates. 2-Alkylpyrazines (X = Me, Et, Pr, i-Pr) displayed a correlation between the logarithms of the concentration ratio of 2- and 3-substituted cations and substituent steric constants. Wider series of substituted pyrazines [X = H, Me, Et, Pr, i-Pr, MeCH(OH), H2N, AcNH] conformed to a multiparameter correlation between the logarithms of the concentration ratio of 2- and 3-substituted cations, on the one hand, and substituent constants σI, σR?, and E s?, on the other. The obtained data on the regioselectivity of amination of pyrazines were interpreted in terms of DFT/PBE/3Z quantum-chemical calculations. Pleiades Publishing, Ltd., 2011.