1201898-95-4Relevant articles and documents
Highly selective allylborations of aldehydes using α,α- disubstituted allylic pinacol boronic esters
Hesse, Matthew J.,Essafi, Stephanie,Watson, Charlotte G.,Harvey, Jeremy N.,Hirst, David,Willis, Christine L.,Aggarwal, Varinder K.
supporting information, p. 6145 - 6149 (2014/06/23)
α,α-Disubstituted allylic pinacol boronic esters undergo highly selective allylborations of aldehydes to give tetrasubstituted homoallylic alcohols with exceptional levels of anti-Z-selectivity (>20:1). The scope of the reaction includes both acyclic and